- 22 December, 2024
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- ONECSIR
| Designation: |
Sr. Principal Scientist
|
| Email Id: | gs_kanade[at]neeri[dot]res[dot]in |
| Qualification: |
B.E.(Electronics), M.E.(Electronics) |
| Specialization: |
Electronics
|
| Address: |
VERTICAL 5A : SOPHISTICATED ENVIRONMENTAL ANALYTICAL FACILITY, NEERI, Nagpur.
|
| Biodata: |
| Sr. No. | Publication Name |
|---|---|
| 1 |
Separation of WPCBs by dissolution of brominated epoxy resins using DMSO and NMP: A comparative study (Chemical Engineering Journal)
|
| 2 |
Role of fluoride induced epigenetic alterations in the development of skeletal fluorosis
Oxidative stress is reported to negatively affect osteoblast cells. Present study reports oxidative and inflammatory signatures in fluoride-exposed human osteosarcoma (HOS) cells, and their possible association with the genes involved in osteoblastic differentiation and bone development pathways. HOS cells were challenged with sublethal concentration (8 mg/L) of sodium fluoride for 30 days and analyzed for transcriptomic expression. In total, 2632 transcripts associated with several biological processes were found to be differentially expressed. Specifically, genes involved in oxidative stress, inflammation, osteoblastic differentiation, and bone development pathways were found to be significantly altered. Variation in expression of key genes involved in the abovementioned pathways was validated through qPCR. Expression of serum amyloid A1 protein, a key regulator of stress and inflammatory pathways, was validated through western blot analysis. This study provides evidence that chronic oxidative and inflammatory stress may be associated with the fluoride-induced impediment in osteoblast differentiation and bone development. |
| 3 |
Separation of WPCBs by dissolution of brominated epoxy resins using DMSO and NMP: A comparative study
Printed circuit boards (PCBs) in electrical and electronic equipment (EEE) abide of valuable and hazardous materials and due to its complex and discrete make up across manufacturers, processing of waste PCBs (WPCBs) is a massive challenge. And therefore either completely novel or improved processes are needed for recycling of WPCBs and recovery of valuable materials from it. Present comparative study, was performed for processing WPCBs using solvents N-methyl-2-pyrrolidone (NMP) and dimethyl sulfoxide (DMSO). Various parameters, which include WPCB sizes; solid to liquid (S/L) ratio; temperature and time, were investigated to understand the WPCBs processing by dissolving bromine epoxy resin using solvents. Results showed that the rate of removal and separation of the bromine epoxy resin (BER) increases with respect to increasing various parameters. Optimum condition of complete separation of WPCBs using NMP were S/L ratio of 1:5, WPCB size/area of 4 mm/16 mm2 and 100 °C for 90 minutes, whereas for DMSO the optimum dissolution of bisphenol A were obtained in S/L ratio of 1:2, size/area of 6 mm/36 mm2 at 90 °C for 90 min. Overall, NMP proves to be better solvent for bromine epoxy resin than DMSO in terms of bisphenol A dissolution and separation of various layers of WPCB. Used solvents can be vaporised–condensed under the decompression for regeneration. This novel process can be an eco-friendly and effective option for separation and recovery of various valuable materials such as metals, glass fibres, etc. from WPCBs. Further research and testing is needed for precise evaluation between two processes using NMP or DMSO solvents, in terms of the valuable material recovery from WPCB and process techno-economics. |
| 4 |
A Proposed Method to Minimize the Global Warming and Environmental Pollution
|
| 5 |
Stress enhances polyunsaturation rich lipid accumulation in Chlorella sp and Chlamydomonas
In the present study, effects of various cultivation conditions on biomass and lipid productivity, detail FAME signature, CO2 biofixation and elemental composition of Chlorella sp. and Chlamydomonas sp. have been investigated. In Chlorella sp., N-depletion has enhanced the lipid productivity by 12.70–14.61%. In Chlamydomonas sp., though the lipid content has increased by 22–26% upon N-depletion, lipid productivity has not changed significantly due to concomitant decrease in biomass productivity by 18–25%. The presence of lipid was also confirmed by FTIR spectroscopic analysis of biomass. The characteristic bands observed at 1744.30 cm?1 (Chlamydomonas sp.) and (Chlorella sp.) were credited to lipids due to C–O mode of the side chain from ester carbonyl group. Extracted lipid was transesterified to FAMEs. Chlorella sp. at N-replete indoor condition has produced the highest weight percentage of C16:0 (26.64%), C18:0 (3.77%) and C18:1 (27.94%). In Chlamydomonas sp., N-replete indoor condition has resulted in maximum content of MUFA (30.12%), LUFA (53.35%), second highest SFA (29.22%) and DUFA (23.23%). Inverse relationship was observed between MUFA and PUFA at all cultivation conditions. In both the microalgae, C16:0, C18:1 (9), C18:2 (9, 12), C18:3 (9, 12, 15) were identified as the major FAMEs which are suitable to be used as biodiesel components |
| 6 |
Biomethanation of vegetable market waste in an anaerobic baffled reactor: Effect of effluent recirculation and carbon mass balance analysis
|
| 7 |
Advanced oxidation processes for the treatment of chlorpyrifos, dimethoate and phorate in aqueous solution
Photo-chemical-transformations of organophosphate pesticides, chlorpyrifos, dimethoate and phorate, using advanced oxidation processes (AOPs) namely UV photolysis, UV/H2O2, UV/Fenton and Fenton systems in aqueous solution were investigated in this work. A laboratory set-up was designed to evaluate and select the optimal oxidation process. Results show that addition of hydrogen peroxide/Fenton's reagent increased the UV degradation rates of all pesticides, and data were simulated through kinetic modeling. Kinetic results evidence pseudo first-order degradation, with the rate constant of reaction as 3.3 × 10-4, 2.07 × 10-2 and 1.88 × 10-2 for chlorpyrifos, dimethoate and phorate, respectively. Furthermore treatment efficiencies obtained for the studied AOPs indicate that UV/Fenton was most efficient for chlorpyrifos (50.3% degradation) and UV/H2O2 for dimethoate (96.9%) and phorate (89.6%). Finally, the identification of degradation products indicated that the UV/H2O2 technique results in the formation of fewer end products, with low toxicity. However, UV irradiation of phorate results in information of more toxic degradation end products such as phorateoxonsulfone. |
| 8 |
Degradation of di through hepta chlorobiphenyl in clophen oil using microorganisms isolated from long term PCB contaminated soil
Present work describes microbial degradation of selected polychlorinated biphenyls (PCBs) congeners in Clophen oil which is used as transformer oil and contains high concentration of PCBs. Indigenous PCBs degrading bacteria were isolated from Clophen oil contaminated soil using enrichment culture technique. A 15 days study was carried out to assess the biodegradation potential of two bacterial cultures and their consortium for Clophen oil with a final PCBs concentration of 100 mg kg?1. The degradation capability of the individual bacterium and the consortium towards the varying range of PCBs congeners (di- through hepta-chlorobiphenyls) was determined using GCMS. Also, dehydrogenase enzyme was estimated to assess the microbial activity. Maximum degradation was observed in treatment containing consortium that resulted in up to 97 % degradation of PCB-44 which is a tetra chlorinated biphenyl whereas, hexa chlorinated biphenyl congener (PCB-153) was degraded up to 90 % by the consortium. This indicates that the degradation capability of microbial consortium was significantly higher than that of individual cultures. Furthermore, the results suggest that for degradation of lower as well as higher chlorinated PCB congeners; a microbial consortium is required rather than individual cultures |
| 9 |
Investigation of polybrominated diphenyl ethers in old consumer products in India
Polybrominated diphenyl ethers (PBDEs) used extensively over the past 3 decades as flame retardants in most types of polymers, all over the world, have been identified as global pollutants. PBDEs pose various health problems such as thyroid hormone disruption, permanent learning and memory impairment, behavioral changes, hearing deficits, delayed puberty onset, fetal malformations, and possibly cancer. Many measurements of PBDEs in various matrices from Sweden, Holland, Japan, the USA, and elsewhere have been reported, but few measurements are available for India. In this study, a preliminary screening of different congeners of PBDEs has been performed in different old electronic and consumer products with an objective to build capacity in order to analyze PBDEs and BFRs. Six different samples, foam from upholstery, motherboard of a computer, children toy composite sample, old vanishing window blind sample, electrical wire sample, and PVC flooring sample, were collected and analyzed for the presence of the following PBDE congeners: BDE-28, BDE-47, BDE-99, BDE-100, BDE-153, BDE-154, BDE-183, and BDE-209. It was found that three out of six samples were positive for the presence of PBDEs. Three congeners were detected in the samples, i.e., BDE-47, BDE-153, and BDE-209, of which, highest concentration was of BDE-209. Among the samples, motherboard of computer showed the highest concentration of BDE-209 followed by window blind and foam from upholstery. The results of this preliminary investigation indicate that PBDEs are still present in the old consumer products which can be an important additional source of exposure to the population. |
| 10 |
Dynamics of effluent treatment plant during commissioning of activated sludge process unit
Industrial effluent treatment plants (ETPs) are very important in protecting the environment and different life forms from harmful industrial waste. Hence, the efficiency of ETPs must be regularly monitored, particularly after major repair or replacement work. Present study evaluated the performance of an ETP over a period of 4 months, during which aeration tank (T1) of the activated sludge unit was replaced with a new one (T2). System had to be maintained operational during this transition, which warranted close monitoring of the system performance due to the daily load of hazardous industrial wastewater. Analysis showed that the raw wastewater was highly variable in composition and contained many hazardous organic and inorganic pollutants, such as heavy metals, bisphenol A and cyanoacetylurea. It showed significant toxicity against HepG2 cells in vitro. However, the ETP was found to successfully treat and detoxify the wastewater. Denaturing gradient gel electrophoresis (DGGE) analysis showed large temporal fluctuations in the ETP microbial community, which is consistent with the variable composition of wastewater. It indicated that functional stability of the ETP was not associated with stability of the microbial community, probably due to high microbial biodiversity and consequently high functional redundancy. In conclusion, the CETP showed consistent level of detoxification and microbial community dynamics after switching to T2, indicating successful development, acclimatization and commissioning of T2. |
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